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While Pep Guardiola's high-flying City are top the Premier League table, Schalke, Wednesday's opponents in the last 16, first-leg clash, are just above the Bundesliga's relegation places.
Schalke are winless in their last three Bundesliga games and sit just above the relegation places in 14th spot.
Chelsea suffered their heaviest defeat for 28 years when they were thrashed 6-0 at Manchester City last weekend, an indignity that came just weeks after a humiliating 4-0 loss at Bournemouth.
Pep Guardiola's side didn't have an easy ride in a full-blooded fifth-round tie against a team 82 places below them in League Two.
Chelsea desperately needed a response after back-to-back humiliating away losses, with last Sunday's 6-0 thrashing by Manchester City following a 4-0 reverse at Bournemouth.
A 6-0 thrashing at the hands of Manchester City on Sunday was Chelsea's heaviest defeat since 1991.
Manchester City remained top, Manchester United moved into the top four and Tottenham are still hanging on.
Manchester City's all-time record goalscorer equalled Alan Shearer's record and helped City thrash Chelsea 6-0.
After two successive draws, Liverpool's 3-0 win helped them take a three-point lead over Manchester City.
Tottenham have kept in touch with Manchester City and Liverpool with three successive wins.